China

Bathing Air -- Brief Introduction of TiO2 Photocatalyst

Today the environment and human healthy suffered from various contaminants, so a new technology of photocatalyst from Japan has got attention extensively. The new product has thorough antibacterial effects and doesn’t do social effect of pollution, so it is called the most advanced antibacterial and purifying technology for houses and cars in the world, and enjoys popularity in the material industry.
With the advance of human material civilization, human has been puzzled by the pollution of exhaust gas of cars, formaldehyde, benzene and mildew, etc. Statistical data indicates that for every year over 100,000 people are killed by indoor pollution in China. Indoor Air Detect Center of China Decorate Association has checked up 200 new cars, about 90 percents have the problem of baneful gas excessive. To find a new technology of depurating environment is the goal that various countries scientists are endeavoring for.
Professor Fujishima and his graduate student Honda discovered the phenomenon below while did experiments in 1972: placed the electrodes made from TiO2 and Pt in the water to form a loop, it can decompose water into oxygen and hydrogen exposing to light if only without electricity. Honda discovered that TiO2 had strong oxidation ability, so he transferred to study the effect of TiO2 in environmental protection that is sterilization, deodorization and decontamination, etc.
The development of photocatalyst:

The products of photocatalyst have been applied in Europe, American, Japan and Korean for 5 years. Especially in Japan, they are applied in various kinds of industries. The data of Japanese business market indicates, after the first development about TiO2 appeared in 1970, the photocatalyst had been developed as commodity in 1990, trial-business reached 0.2 billion yen in 1997, 1.2 billion yen in 1998, 4 billion yen in 1999 and over 100 billion yen in 2001. The growing speed was striking and the demand of present market is huge. The Japanese business agency boldly forecasted that the production value of the related industries derived from applying TiO2 would reach over 100 billions ~ 500 billions yen. Only in view of remarkable achievement in Japanese market, and the basic survival condition of human being, the development of potential market will be unlimited.
TiO2 photocatalyst principle:

Nanometer photocatalyst are made from TiO2 grains, the sizes of which are under 20nm. After they absorb UV in sunshine and illuminate lamp-house, the electrons on them are activated by UV and flies off, then produce electron holes, which have strong oxidation ability (the holes are produced, when the electrons are flying off). The electron has strong deoxidization ability, will produce oxidation anion free radicals and oxyhydrogen free radicals after reacting with H20 and O2 in air. They have strong oxidation ability, and can decompose the organic, contaminants, fume, and bacteria into hurtles CO2 and H2O . At the same time, the electrons make deoxidization reaction to deoxidize the oxygen in air.

[1]

TiO2 photocatalyst principle: [2]
Application:
1, Sterilization, restraining virus: TiO2 photocatalyst can destroy the membrane of the cell; solid the protein of virus, restrain the virus activation, and catch, kill aerobic bacteria up to 99.97%.
a. It can kill coliform, green suppuration bacillus, golden grape coccus, mildew, suppuration fungus, etc.
The ability of sterilization can be tested through coliform and golden grape coccus. At the beginning, there are 3.3x105 coliforms and 3.2x105 golden grape coccus. After 24 hours' reaction, there are only 10.
b. It can decompose anaphylactogen of air and reduce anaphylactia and pant.
c. Restrain the virus, and can prevent it.
2,Removing the environmental pollution:

a , The oxyhydrogen free radical produced by TiO2 photocatalyst can destroy organic molecules firstly and make it become single gas molecules, so it can accelerate decomposing the organic and gas and advance the efficiency of air cleaning.
b , TiO2 , photocatalyst has stronger oxidation ability than ozone and anion, stronger absorbability than active carbon, and has the efficacy (decomposing bacteria), which the active carbon doesn't have. According to authoritative laboratory test in Europe and America , the deodorization ability is 150 times stronger than high-efficacy fiber active carbon, equivalent to 500 active carbon refrigerator deodorant.
c , Photocatalyst has strong efficacy of preventing mildew. The cloth packaged food utilizing photocatalyst can obviously suppress going mould. It can keep fresh in 10 days. According to the experiment, the efficacy spraying over 1000 square meters is equivalent to the air purifying ability of 70 silver birch. The world of photocatalyst is fresh and healthy like nature.
d , It has strong efficacy of decomposing formaldehyde, benzene, ammonia and other organics that are discharged by fitment materials.
e , It can eliminate the contaminants such as CO,SO2, NO and oxyhydrogen compound.
f , It can eliminate the smoke, garbage smell, life smell effectively.
The function of purification: [3]

3 , Hydrophile and antipollution: We only need clean the object using water when the dust on it which has been disposed by TiO2 . Because TiO2 have the ability of hydrophile and decomposing the crease, the dust can fall down with water and make sure the dust is difficult to attach, and make the appearance clean.
The principle of Hydrophile [4]
4 , Defending UV : the character of absorbing UV of TiO2 photocatalyst makes the surface sprayed keep away from aging action, so it has a longer using life.
5 , Keep away from rust and depigment
5Keep the metal away from rust, and depigment.
The applications:

a, Room, sitting room, bedroom, kitchen, furniture, decorate things
b, Hotel, the meeting room, the banquet hall, pharmaceutical factory, food factory, market, cinema, the internet café, the office building, the operating room of hospital and the ward, the public place of entertainment, the gymnasium.
c, All kinds of vehicles.
“ROOT” series photocatalyst products include TiO2 power and plasm, photocatalyst air purifier, nanometer Ag photocatalyst purifier, photocatalyst indoor air purifier, photocatalyst cars' air purifier, anion portable purifier, anion economize purifying light. Our products adopt advanced technology. Equivalent to other congener products, they have these traits downwards:
a, New technology. Adopt modern high-tech nanometer technology. Make TiO2 , nanometer Ag and Sio2 compound, and prepare a unique nanometer photocatalyst material. It has strong redox ability that makes it decompose various organic and inorganic matters. Simultaneously it can keep on sterilizing for 24 hours without light.
b, High purity. The content of TiO2 in the products = 98%. Adopt high purity and high dosage mulriple photocatalyst filter.
c, High efficacy. The sterilization rate of photocatalyst air purifier reaches over 99%. The rate of deodorization is 99%, and creates a fresh anion environment. It is nonpoisonous and tasteless, and will not produce other contaminants and radiation matters. It has persistence characteristic.
d, Pertinence. Customers can customize the diameter of the TiO2 grains and append other materials to suit their demands. and pertinence and efficiency of our products are enlarged.
e, Popular and convenient. The products are novel, small, convenient, and easy to take with. The scope of application is extensive, including in the rooms, outdoors, in cars, public and vehicles, etc.
f, Safe. The brief content is TiO2 , it can use as food additive, was approved through U.S.A. FDA. It has been extensively applied in cosmetic, brightening agent, nonpoisonous white dye, and it's very safe.
g, Persistence characteristic. Because TiO2 is steady, and only use as catalyzer, it can function forever theoretically.
ROOT photocatalyst compares with other air purifiers below:

Air purifier

Theory

Merit

Deficiency

Formaldehyde catcher

Spray or brush the plies fitted up with formaldehyde catcher, which is consumed as reacting with formaldehyde, producing another chemical. But it cannot decompose the formaldehyde molecules into innocuous substance,

Eliminating formaldehyde

It just aims at eliminating formaldehyde but benzene, ammonia and TVOC. It cannot be used on walls, floor and sofas, and the use is incomprehensive. The reactive time is short. In general, it is only a simple means to meet an emergency.

Air balmy sorbent

It is a volatile chemical, which conceals bad air through volatilizing special scent

Make air balmy

A mixed gas is produced which brings people good feeling and illusion, but it cannot eliminate baneful gas. It must be used frequently and brings body some blight at a long-term use.

 

Active carbon sorbent

 

It sorbs big gas molecules and suspending grains owing to its porous character, e.g. smoke, dust, etc. It purifies air through forcing air to circulate by aerator.

Can eliminate smoke, dust, etc in air

The filters must be replaced termly, the efficiency is low and it cannot deracinate the baneful gas.

 

Ozone sterilization

Utilize air circulation of air conditioner, send high density ozone produced by automobile disinfector to each corner

Won’t remain any baneful material, and won’t produce the second pollution

There are ozone smell in carriages after sterilization, and must be used termly.

Anion generator

Increase the anions of air. The anions can depress bacteria, virus, and eliminate the smell, make the air clean

Can depress bacteria, virus, and eliminate the smell, make the air clean

Increase the anions in the air make chauffeur’ mind sober, but is helpless to eliminate the intrinsic contamination

ROOT photocatalyst

 

Adopt nanometer TiO2 as catalyst; produce active matters by photocatalyst reaction in air. So it can clean the air, be antibacterial, defend moudly

It doesn’t be consumed and declined along with the time, because it doesn’t participate in redox directly as catalyst, it will be efficient for long It can efficiently decompose and eliminate all kinds of organic materials and partial inorganic baneful gas, sterilize, deodorize, prevent pollution etc. It creates a anion environment for people. Using and taking are convenient. Chinese Technology Association project institute approves the method.

 

 

From the comparison above, we know that ROOT series products have better capability and market potential.
Photocatalyst disposes of air pollution indoor most ideally, downright, completely, efficiently and it has a bright market.
[1] From A. Fujishima and K. Honda: 238,37(1972)
[2], [3], [4] from Beijing Ntide Environmental Technology Inc., www.ntide.com:Photocatalyst Knowledge
We are grateful for the data. Thank you very much!
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